Explore the earliest forms of batteries and the arrival of electricity.
One of the most remarkable and novel discoveries in the last 400 years was electricity. We might ask, “Has electricity been around that long?” The answer is yes, and perhaps much longer, but its practical use has only been at our disposal since the mid to late 1800s, and in a limited way at first. One of the earliest public works gaining attention was enlightening the 1893 Chicago’s World Columbia Exposition with 250,000 light bulbs, and illuminating a bridge over the river Seine during the 1900 World Fair in Paris.
The use of electricity may go back further. While constructing a railway in 1936 near Baghdad, workers uncovered what appeared to be a prehistoric battery, also known as the Parthian Battery. The object dates back to the Parthian period and is believed to be 2,000 years old. The battery consisted of a clay jar that was filled with a vinegar solution into which an iron rod surrounded by a copper cylinder was inserted. This device produced 1.1 to 2.0 volts of electricity. Figure 1 illustrates the Parthian Battery.
Figure 1: Parthian Battery. A clay jar of a prehistoric battery holds an iron rod surrounded by a copper cylinder. When filled with vinegar or electrolytic solution, the jar produces 1.1 to 2 volts.
Not all scientists accept the Parthian Battery as a source of energy. It is possible that the device was used for electroplating, such as adding a layer of gold or other precious metals to a surface. The Egyptians are said to have electroplated antimony onto copper over 4,300 years ago. Archeological evidence suggests the Babylonians were the first to discover and employ a galvanic technique in the manufacturing of jewelry by using an electrolyte based on grape juice to gold plate stoneware. The Parthians, who ruled Baghdad (ca. 250 BC), may have used batteries to electroplate silver.
One of the earliest methods to generate electricity in modern times was through creating a static charge. In 1660, Otto von Guericke constructed an electrical machine using a large sulfur globe which, when rubbed and turned, attracted feathers and small pieces of paper. Guericke was able to prove that the sparks generated were electrical in nature.
In 1744, Ewald Georg von Kleist, developed the Leyden jar that stored static charge in a glass jar lined with metallic foil on the in- and outside of the container. These two electrodes formed a capacitor. The scientists that also included Peter van Musschenbroek, professor in Diusburg, Utrecht and Leiden, thought that electricity was a fluid and could be captured in a bottle. This did not happen and the scientists received heavy shocks studying electrostatics.
The first practical use of static electricity was the “electric pistol,” which Alessandro Volta (1745–1827) invented. He thought of providing long-distance communications, albeit only one Boolean bit. An iron wire supported by wooden poles was to be strung from Como to Milan, Italy. At the receiving end, the wire would terminate in a jar filled with methane gas. To signal a coded event, an electrical spark would be sent by wire for the purpose of detonating the electric pistol. This communications link was never built. Figure 1-2 shows a pencil rendering of Alessandro Volta.
Figure 2: Alessandro Volta, inventor of the electric battery
Volta’s discovery of the decomposition of water by an electrical current laid the foundation of electrochemistry.
Courtesy of Cadex
In 1791, while working at Bologna University, Luigi Galvani discovered that the muscle of a frog would contract when touched by a metallic object. This phenomenon became known as animal electricity. Prompted by these experiments, Volta initiated a series of experiments using zinc, lead, tin and iron as positive plates (cathode); and copper, silver, gold and graphite as negative plates (anode). The interest in galvanic electricity soon became widespread.
Volta discovered in 1800 that certain fluids would generate a continuous flow of electrical power when used as a conductor. This discovery led to the invention of the first voltaic cell, more commonly known as the battery. Volta discovered further that the voltage would increase when voltaic cells were stacked on top of each other. Figure 3 illustrates such a serial connection.
Figure 1-3: Volta’s experiments with the electric battery in 1796
In the same year, Volta released his discovery of a continuous source of electricity to the Royal Society of London. No longer were experiments limited to a brief display of sparks that lasted a fraction of a second. An endless stream of electric current now seemed possible.
France was one of the first nations to officially recognize Volta’s discoveries. This was during a time when France was approaching the height of scientific advancements and new ideas were welcomed with open arms, helping to support of the country’s political agenda. By invitation, Volta addressed the Institute of France in a series of lectures at which Napoleon Bonaparte was present as a member of the institute (see Figure 4).
Figure 4: Volta’s experimentations at the Institute of France
Volta’s discoveries so impressed the world that in November 1800 the French National Institute invited him to lectures at events in which Napoleon Bonaparte participated. Napoleon helped with the experiments, drawing sparks from the battery, melting a steel wire, discharging an electric pistol and decomposing water into its elements.
Courtesy of Cadex
In 1800, Sir Humphry Davy, inventor of the miner’s safety lamp, began testing the chemical effects of electricity and found out that decomposition occurred when passing electrical current through substances. This process was later called electrolysis.
He made new discoveries by installing the world’s largest and most powerful electric battery in the vaults of the Royal Institution of London. Connecting the battery to charcoal electrodes produced the first electric light. Witnesses reported that his voltaic arc lamp produced “the most brilliant ascending arch of light ever seen.”
In 1802, William Cruickshank designed the first electric battery for mass production. Cruickshank arranged square sheets of copper with equal-sized sheets sizes of zinc. These sheets were placed into a long rectangular wooden box and soldered together. Grooves in the box held the metal plates in position. The sealed box was then filled with an electrolyte of brine, or a watered-down acid. This resembled the flooded battery that is still with us today. Figure 5 illustrates the battery workshop of Cruickshank.
Figure 5: Cruickshank and the first flooded battery. William Cruickshank, an English chemist, built a battery of electric cells by joining zinc and copper plates in a wooden box filled with an electrolyte solution. This flooded design had the advantage of not drying out with use and provided more energy than Volta’s disc arrangement.
Courtesy of Cadex
In 1836, John F. Daniell, an English chemist, developed an improved battery that produced a steadier current than earlier devices. Until this time, all batteries were primary, meaning they could not be recharged. In 1859, the French physician Gaston Planté invented the first rechargeable battery. It was based on lead acid, a system that is still used today.
In 1899, Waldmar Jungner from Sweden invented the nickel-cadmium battery (NiCd), which used nickel for the positive electrode (cathode) and cadmium for the negative (anode). High material costs compared to lead acid limited its use.
Two years later, Thomas Edison produced an alternative design by replacing cadmium with iron. Low specific energy, poor performance at low temperature and high self-discharge limited the success of the nickel-iron battery. It was not until 1932 that Shlecht and Ackermann achieved higher load currents and improved the longevity of NiCd by inventing the sintered pole plate. In 1947, Georg Neumann succeeded in sealing the cell.
For many years, NiCd was the only rechargeable battery for portable applications. In the 1990s, environmentalists in Europe became concerned about environmental contamination if NiCd were carelessly disposed; they began to restrict this chemistry and asked the consumer industry to switch to Nickel-metal-hydride (NiMH), a more environmentally friendly battery. NiMH is similar to NiCd; however these nickel-based chemistries are being replaced by lithium-ion.
Most research activities today revolve around improving lithium-based systems. Besides powering cellular phones, laptops, digital cameras, power tools and medical devices, Li-ion is also used for electric vehicles and satellites. The battery has a number of benefits, most notably its high specific energy, simple charging, low maintenance and being environmentally benign.
Generating electricity through magnetism came relatively late. In 1820, André-Marie Ampère (1775–1836) noticed that wires carrying an electric current were at times attracted to, and at other times repelled from, one another. In 1831, Michael Faraday (1791–1867) demonstrated how a copper disc provided a constant flow of electricity while revolving in a strong magnetic field. Faraday, assisting Humphry Davy and his research team, succeeded in generating an endless electrical force as long as the movement between a coil and magnet continued. This led to the invention of the electric generator, as well as the electric motor by reversing the process.
Shortly thereafter, transformers were developed that converted alternating current (AC) to any desired voltage. In 1833, Faraday established the foundation of electro-chemistry on which the Faraday law is based. Faraday’s law of induction relates to electromagnetism found in transformers, inductors, and many types of electrical motors and generators.
Once the relationship with magnetism was understood, large generators were built to produce a steady flow of electricity. Motors followed that enabled mechanical movement and Thomas Edison’s light bulb appeared to conquer darkness.
Early electrical plants produced direct current (DC), which could deliver electricity no more than 3km (~2 miles). In around 1886, the Niagara Falls Power Company offered $100,000 for a method to transmit electricity over a long distance. When no one responded, the world’s brightest minds met in London, England. The prize was eventually given to Nicola Tesla (1856–1943), a Croatian immigrant who created the AC transmission system.
DC systems run on low voltage and required heavy wires; AC could be transformed to higher voltages for transmission over light wires and then reduced for use. The older generation supported DC while younger geniuses gravitated toward AC. Thomas Edison was dead set against AC, giving electrocution as a reason.
AC became the accepted norm and George Westinghouse, an American inventor and manufacturer, began developing the Tesla system. A war on current broke out with Edison and Westinghouse becoming adversaries over the choice of current.
Figure 6: Nikola Tesla
In 1883, Westinghouse created a lighting system for Niagara Falls using AC current and in 1893 lit up Chicago's World Columbian Exposition to everyone’s amazement (Figure 7). Westinghouse then built three large generators to transform energy from the Niagara Falls to electricity. Three-phase AC technology developed by Tesla enabled the transmission of electric power over great distances cheaply. Electricity was thus made widely available to humanity to improve the quality of life.
Figure 7: 250,000 light bulbs illuminate Chicago's World Columbian Exposition in 1893.
The success of the electric light led to building three large hydro generators at Niagara Falls.
Courtesy of the Brooklyn Museum Archives. Goodyear Archival Collection
Telecommunications by wire built along the railways mostly operated by primary batteries that needed frequent replacement. Telex was digital in that the batteries activated a series of relays. The price to send a message was based on the number of relay clicks required. In the mid-1800s, telegraphy opened new careers for bright young men. Staff staff operating of these devices moved into the growing middle class, far removed from mills and mines fraught with labor, dirt and danger. Steel magnate Andrew Carnegie recalled his early days as a telegraphy messenger, and Alfred Hitchcock started his career as an estimator before becoming an illustrator.
The invention of the electronic vacuum tube in the early 1900s formed the significant next step towards high technology. It enabled frequency oscillators, signal amplifications and digital switching. This led to radio broadcasting in the 1920s and the first digital computer, called ENIAC, in 1946. The discovery of the transistor in 1947 paved the way for the arrival of the integrated circuit 10 years later, and the microprocessor ushered in the Information Age, forever changing the way we live and work.
Humanity has become dependent on electricity and with increased mobility people gravitate towards portable power involving the battery. As the battery improves further, more tasks will be made possible with this portable power source.
Last Updated 2015-08-21
Comments are intended for "commenting," an open discussion amongst site visitors. Battery University monitors the comments and understands the importance of expressing perspectives and opinions in a shared forum. However, all communication must be done with the use of appropriate language and the avoidance of spam and discrimination.
If you have a question, require further information, have a suggestion or would like to report an error, use the "contact us" form or email us at: [email protected]. While we make all efforts to answer your questions accurately, we cannot guarantee results. Neither can we take responsibility for any damages or injuries that may result as a consequence of the information provided. Please accept our advice as a free public support rather than an engineering or professional service.