What everyone should know about Battery Chargers
A good charger provides the base for well-performing and durable batteries. In a price-competitive market chargers often receive low priority. The battery and charger must go together like horse and carriage (Figure 1), and this is not always the case. Engineers are often not fully aware of the complex power requirement of a portable device and the need to charge under adverse conditions.
Figure 1: Battery and charger must go together like horse and carriage
One party does not deliver without the other.
Chargers are divided into personal and industrial, “smart” and “dumb,” slow, fast and ultra-fast types. Consumer products come with a low-cost personal charger that performs well when used as directed. The industrial charger is often made by a third party and includes special features, such as charging at adverse temperatures. Although batteries operate below freezing, not all chemistries can be charged when cold and most Li-ion falls into this category. Lead and nickel-based batteries accept charge but at a lower rate.
Some Li-ion chargers (Cadex) include a wake-up feature, or “boost,” to allow recharging if a Li-ion battery have fallen asleep due to over-discharge. A sleep condition can occur when storing the battery in a discharged state and the self-discharge brings the voltage to the cut-off point. A regular charger treats such a battery as unserviceable and the packs are discarded. Boost applies a small charge current to raise the voltage to between 2.20 and 2.90V/cell and activate the protection circuit, at which point a normal charge commences. Caution applies if Li-ion has dwelled below 1.5V/cell for a week or longer.
Lead- and lithium-based chargers operate on Constant Current Constant Voltage (CCCV) by which the voltage is capped when reaching a set limit. At this point of the charge cycle, the battery begins to saturate and the current drops. Full-charge occurs when the current drops to a set level. Lead acid requires a periodic full saturation to prevent sulfation.
Nickel-based batteries charge with constant current and the voltage is allowed to fluctuate freely. This can be compared to lifting a weight with an elastic band where the hand moves ahead of the load. Full charge detection occurs when observing a slight voltage drop after a steady rise. This method is known as the Delta Voltage Delta Temperature (DVDT) and works well with rapid and fast charge. To safeguard against anomalies, such as shorted or mismatched cells, the charger should include a plateau timer to terminate charge if no voltage delta is measured, as well as a temperature sensors.
A temperature rise is normal with nickel-based batteries, especially when reaching the 70 percent charge level. The reason for this is a decrease in charge efficiency and the charge current should be lowered to limit stress. When “ready,” the battery must cool down. If the temperature stays above ambient, then the charger is not performing right and the battery should be removed. Extended trickle charge on nickel-based batteries inflicts damage. NiCd and NiMH should not be left in the charger unattended for weeks and months. If not required, store them in a cool place and apply a charge before engagement.
Lithium-based should always stay cool on charge. Discontinue using the battery and/or charger if the battery heats up on charge. Li ion cannot absorb over-charge and therefore does not receive trickle charge when full. It is not necessary to remove Li-ion from the charger, however, if not used for a week or more, it is always best to place the pack in a cool place and recharge before use.
The most basic charger is the overnight charger, also known as slow charger. This goes back to the old nickel-cadmium days where a simple charger applied a fixed charge of about 0.1C (one-tenth of the rated capacity) as long as the battery was connected. Slow chargers have no full-charge detection; the charge stays engaged and a full charge of an empty battery takes 14–16 hours. When fully charged, the slow charger keeps NiCd lukewarm to the touch. Because of its reduced ability to absorb over-charge, NiMH should not be charged on a slow charger. Low-cost consumer chargers to charge C AA and AAA cells often use this charger method, so do some children’s toys.
The rapid charger falls between the slow and fast charger and is used in consumer products. The charge time of an empty pack is 3–6. When full, the charger switches to “ready.” Most rapid chargers include temperature sensing to safely charge a faulty battery.
The fast charger offers several advantages and the obvious one is shorter charge times. Short charge times demand tighter communication between the charger and battery. At a charge rate of 1C, which the fast charger typically uses, an empty NiCd and NiMH charges in a little more than an hour. As the battery approaches full charge, some nickel-based chargers reduce the current to adjust to the lower charge acceptance. The fully charged battery switches to trickle charge, also known as maintenance charge. Most of today’s nickel-based chargers have a reduced trickle charge to also accommodate NiMH.
Li-ion charges are most efficient and charge the battery to 70 percent in less than an hour. The extra time is devoted for the long saturation charge that is not mandatory as it is for lead acid. In fact, it is better not to fully charge Li-ion as it will last longer. Of all chargers, the Li-ion charger is the most simplistic. No trickery applies to improve battery performance and longevity. Only the CCCV method works.
Lead acid cannot be fast-charged and the term “fast-charge” is a misnomer. Most lead acid chargers charge the battery in 14–16 hours; anything slower is a compromise. Lead acid can be charged to 70 percent in about eight hours; the all-important saturation charge takes up the remaining time. A partial charge is fine provided the lead acid occasionally receives a fully saturated charge to prevent sulfation.
Last Updated: 26-May-2015
Batteries In A Portable World
The material on Battery University is based on the indispensable new 4th edition of "Batteries in a Portable World - A Handbook on Rechargeable Batteries for Non-Engineers" which is available for order through Amazon.com.
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Table of Contents
-
Introduction 4>
- BU-001: Sharing Battery Knowledge
- BU-002: Introduction
- BU-003: Dedication
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Crash Course on Batteries 4>
- BU-101: When Was the Battery Invented?
- BU-102: Early Innovators
- BU-103: Global Battery Markets
- BU-103a: Battery Breakthroughs: Myth or Fact?
- BU-104: Getting to Know the Battery
- BU-104a: Comparing the Battery with Other Power Sources
- BU-104b: Battery Building Blocks
- BU-104c: The Octagon Battery – What makes a Battery a Battery
- BU-105: Battery Definitions and what they mean
- BU-106: Advantages of Primary Batteries
- BU-106a: Choices of Primary Batteries
- BU-107: Comparison Table of Secondary Batteries
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Battery Types 4>
- BU-201: How does the Lead Acid Battery Work?
- BU-201a: Absorbent Glass Mat (AGM)
- BU-201b: Gel Lead Acid Battery
- BU-202: New Lead Acid Systems
- BU-203: Nickel-based Batteries
- BU-204: How do Lithium Batteries Work?
- BU-205: Types of Lithium-ion
- BU-206: Lithium-polymer: Substance or Hype?
- BU-208: Cycling Performance
- BU-209: How does a Supercapacitor Work?
- BU-210: How does the Fuel Cell Work?
- BU-210a: Why does Sodium-sulfur need to be heated
- BU-210b: How does the Flow Battery Work?
- BU-211: Alternate Battery Systems
- BU-212: Future Batteries
- BU-214: Summary Table of Lead-based Batteries
- BU-215: Summary Table of Nickel-based Batteries
- BU-216: Summary Table of Lithium-based Batteries
- BU-217: Summary Table of Alternate Batteries
- BU-218: Summary Table of Future Batteries
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Packaging and Safety 4>
- BU-301: A look at Old and New Battery Packaging
- BU-301a: Types of Battery Cells
- BU-302: Series and Parallel Battery Configurations
- BU-303: Confusion with Voltages
- BU-304: Why are Protection Circuits Needed?
- BU-304a: Safety Concerns with Li-ion
- BU-304b: Making Lithium-ion Safe
- BU-304c: Battery Safety in Public
- BU-305: Building a Lithium-ion Pack
- BU-306: What is the Function of the Separator?
- BU-307: How does Electrolyte Work?
- BU-308: Availability of Lithium
- BU-309: How does Graphite Work in Li-ion?
- BU-310: How does Cobalt Work in Li-ion?
- BU-311: Battery Raw Materials
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Charge Methods 4>
- BU-401: How do Battery Chargers Work?
- BU-401a: Fast and Ultra-fast Chargers
- BU-402: What Is C-rate?
- BU-403: Charging Lead Acid
- BU-404: What is Equalizing Charge?
- BU-405: Charging with a Power Supply
- BU-406: Battery as a Buffer
- BU-407: Charging Nickel-cadmium
- BU-408: Charging Nickel-metal-hydride
- BU-409: Charging Lithium-ion
- BU-409a: Why do Old Li-ion Batteries Take Long to Charge?
- BU-409b: Charging Lithium Iron Phosphate
- BU-410: Charging at High and Low Temperatures
- BU-411: Charging from a USB Port
- BU-412: Charging without Wires
- BU-413: Charging with Solar, Turbine
- BU-413a: How to Store Renewable Energy in a Battery
- BU-414: How do Charger Chips Work?
- BU-415: How to Charge and When to Charge?
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Discharge Methods 4>
- BU-501: Basics about Discharging
- BU-501a: Discharge Characteristics of Li-ion
- BU-502: Discharging at High and Low Temperatures
- BU-503: Determining Power Deliver by the Ragone Plot
- BU-504: How to Verify Sufficient Battery Capacity
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"Smart" Battery 4>
- BU-601: How does a Smart Battery Work?
- BU-602: How does a Battery Fuel Gauge Work?
- BU-603: How to Calibrate a “Smart” Battery
- BU-603a: Calibrating SMBus Batteries with Impedance Tracking
- BU-604: How to Process Data from a “Smart” Battery
- Testing and Calibrating Smart Batteries
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From Birth to Retirement 4>
- BU-701: How to Prime Batteries
- BU-702: How to Store Batteries
- BU-703: Health Concerns with Batteries
- BU-704: How to Transport Batteries
- BU-704a: Shipping Lithium-based Batteries by Air
- BU-704b: CAUTION & Overpack Labels
- BU-704c: Class 9 Label
- BU-704d: NFPA 704 Rating
- BU-704e: Battery for Personal and Fleet Use
- BU-705: How to Recycle Batteries
- BU-705a: Battery Recycling as a Business
- BU-706: Summary of Do's and Don'ts
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How To Prolong Battery Life 4>
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General 4>
- BU-801: Setting Battery Performance Standards
- BU-801a: How to Rate Battery Runtime
- BU-801b: How to Define Battery Life
- BU-802: What Causes Capacity Loss?
- BU-802a: How does Rising Internal Resistance affect Performance?
- BU-802b: What does Elevated Self-discharge Do?
- BU-802c: How Low can a Battery be Discharged?
- BU-803: Can Batteries Be Restored?
- BU-803a: Cell Matching and Balancing
- BU-803b: What causes Cells to Short?
- BU-803c: Loss of Electrolyte
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Lead Acid 4>
- BU-804: How to Prolong Lead-acid Batteries
- BU-804a: Corrosion, Shedding and Internal Short
- BU-804b: Sulfation and How to Prevent it
- BU-804c: Acid Stratification and Surface Charge
- BU-805: Additives to Boost Flooded Lead Acid
- BU-806: Tracking Battery Capacity and Resistance as part of Aging
- BU-806a: How Heat and Loading affect Battery Life
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Nickel-based 4>
- BU-807: How to Restore Nickel-based Batteries
- BU-807a: Effect of Zapping
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Lithium-ion 4>
- BU-808: How to Prolong Lithium-based Batteries
- BU-808a: How to Awaken a Sleeping Li-ion
- BU-808b: What Causes Li-ion to Die?
- BU-808c: Coulombic and Energy Efficiency with the Battery
- BU-809: How to Maximize Runtime
- BU-810: What Everyone Should Know About Aftermarket Batteries
- BU-811: Assuring Minimum Operational Reserve Energy (MORE)
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Battery Testing and Monitoring 4>
- BU-901: Fundamentals in Battery Testing
- BU-901b: How to Measure the Remaining Useful Life of a Battery
- BU-902: How to Measure Internal Resistance
- BU-902a: How to Measure CCA
- BU-903: How to Measure State-of-charge
- BU-904: How to Measure Capacity
- BU-905: Testing Lead Acid Batteries
- BU-905a: Testing Starter Batteries in Vehicles
- BU-905b: Knowing when to Replace a Starter Battery
- BU-906: Testing Nickel-based Batteries
- BU-907: Testing Lithium-based Batteries
- BU-907a: Battery Rapid-test Methods
- BU-907b: Advancements in Battery Testing
- BU-907c: Cloud Analytics in Batteries
- BU-908: Battery Management System (BMS)
- BU-909: Battery Test Equipment
- BU-910: How to Repair a Battery Pack
- BU-911: How to Repair a Laptop Battery
- BU-915: Testing Battery with EIS
- BU-916: Deep Battery Diagnostics
- BU-917: In Search for Performance Transparency with Batteries
- BU-918: Battery Endurance Plan
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Amazing Value of a Battery 4>
- BU-1001: Batteries in Industries
- BU-1002: Electric Powertrain, then and now
- BU-1002a: Hybrid Electric Vehicles and the Battery
- BU-1002b: Environmental Benefit of the Electric Powertrain
- BU-1003: Electric Vehicle (EV)
- BU-1003a: Battery Aging in an Electric Vehicle (EV)
- BU-1004: Charging an Electric Vehicle
- BU-1005: Does the Fuel Cell-powered Vehicle have a Future?
- BU-1006: Cost of Mobile and Renewable Power
- BU-1007: Net Calorific Value
- BU-1008: Working towards Sustainability
- BU-1009: Battery Paradox - Afterword
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Information 4>
- BU-1101: Glossary
- BU-1102: Abbreviations
- BU-1103: Bibliography
- BU-1104: About the Author
- BU-1105: About Cadex (Sponsor)
- BU-1106: Author's Creed
- BU-1107: Disclaimer
- BU-1108: Copyright
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Learning Tools 4>
- BU-1501 Battery History
- BU-1502 Basics about Batteries
- BU-1503 How to Maintain Batteries
- BU-1504 Battery Test & Analyzing Devices
- BU-1505 Short History of Cadex
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Battery Articles 4>
- Perception of a Battery Tester
- Green Deal
- Risk Management in Batteries
- Predictive Test Methods for Starter Batteries
- Why Mobile Phone Batteries do not last as long as an EV Battery
- Battery Rapid-test Methods
- How to Charge Li-ion with a Parasitic Load
- Ultra-fast Charging
- Assuring Safety of Lithium-ion in the Workforce
- Diagnostic Battery Management
- Tweaking the Mobile Phone Battery
- Battery Test Methods
- Battery Testing and Safety
- How to Make Battery Performance Transparent
- Battery Diagnostics On-the-fly
- Making Battery State-of-health Transparent
- Batteries will eventually die, but when and how?
- Why does Pokémon Go rob so much Battery Power?
- How to Care for the Battery
- Tesla’s iPhone Moment — How the Powerwall will Change Global Energy Use
- Painting the Battery Green by giving it a Second Life
- Charging without Wires — A Solution or Laziness
- What everyone should know about Battery Chargers
- A Look at Cell Formats and how to Build a good Battery
- Battery Breakthroughs — Myth or Fact?
- Rapid-test Methods that No Longer Work
- Shipping Lithium-based Batteries by Air
- How to make Batteries more Reliable and Longer Lasting
- What causes Lithium-ion to die?
- Safety of Lithium-ion Batteries
- Recognizing Battery Capacity as the Missing Link
- Managing Batteries for Warehouse Logistics
- Caring for your Starter Battery
- Giving Batteries a Second Life
- How to Make Batteries in Medical Devices More Reliable
- Possible Solutions for the Battery Problem on the Boeing 787
- Impedance Spectroscopy Checks Battery Capacity in 15 Seconds
- How to Improve the Battery Fuel Gauge
- Examining Loading Characteristics on Primary and Secondary Batteries
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Language Pool 4>
- BU-001: Compartir conocimiento sobre baterías
- BU-002: Introducción
- BU-003: Dedicatoria
- BU-104: Conociendo la Batería
- BU-302: Configuraciones de Baterías en Serie y Paralelo
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Batteries in a Portable World book 4>
- Change-log of “Batteries in a Portable World,” 4th edition: Chapters 1 - 3
- Change-log of “Batteries in a Portable World,” 4th edition: Chapters 4 - 10