How to Care for the Battery
The numbers of battery conferences are growing, but the agendas are similar — portraying a super battery that does not yet exist. With a grant of $120 million from the US Department of Energy, the Joint Centre for Energy Storage Research (JCESR) wants to develop a battery that is “five times more powerful and five times cheaper than current systems in five years.” They call this the 5-5-5 Plan. Universities are also involved but battery manufacturers are much further ahead. Additives that govern performance to a large extent are guarded as a top secret by each manufacturer.
Toyota had already been searching for the super battery in 1925. They called this the “Sakichi battery” after Sakichi Toyoda, the inventor of Japan’s power loom and the founder of Toyota Motors. He is often called the father of the Japanese industrial revolution. It is said that Mr. Toyoda promised the yet-to-be-claimed prize of 1 million yen for a storage battery that produces more energy than gasoline. To qualify for the price, the Sakichi battery must be durable and quick to charge.
Progress is being made but not without roadblocks. Lithium-air proposed in the 1970’s with a theoretical specific energy resembling gasoline is being delayed due to air-purity issues; the urban air that the battery “breaths” is not clean enough. The promising lithium-metal introduced in the 1980s still grows dendrites, leading to violent events with flame if an electrical short develops. There is much talk about the solid-state battery that shares similarity with lithium-metal, but scientists must also solve the dendrite problem here, as well as improve low conductivity at cooler temperatures and short cycle life. Lithium sulfur may be close to commercialization but the short cycle life also troubles this system. The redox-flow battery could offer a solution for large battery systems by pumping “charged” fluids from external tanks through a membrane, but this refinery-like battery suffers from corrosion. There is a glimmer of hope for Li-ion by coating the anode with graphene, a layer that is only one atom thick. This is said to quadruple the capacity, but such a battery is still miles away.
As part of a survey, a consulting firm asked me what advancements battery users want to see in a battery and he gave me list of options to choose from. Will this be a 25 percent increase in energy density; a 25 percent boost in discharge rate; a 25 percent improvement in temperature range and safety; or will this be a 25 percent reduction in size and weight?
I explained that a better battery does not rest on such enhancements alone but in knowing the performance of each pack in the field. This is seldom mentioned and a biomed technician said: “Batteries are the most abused components; staff care little about them and only do the bare minimum to service them.” He added further that, “references to battery maintenance are vague and hidden deep inside service manuals.”
Checking into battery usage in healthcare, I came across a US FDA survey that says “up to 50 percent of service calls in hospitals surveyed relate to battery issues.” Healthcare professionals at AAMI (Association for the Advancement of Medical Instruments) further stated that “battery management emerged as a top 10 medical device challenge.”
To solve these issues, device manufacturers mandate to replace the batteries on a date-stamp of 2 to 3 years of use. Batteries have improved and live longer; they also carry a higher price tag. Date-stamping has resulted in batteries being replaced too soon and a DOE report reflects this by saying that every year roughly one million lithium-ion batteries are discarded with most packs still having a capacity of up to 80 percent.
“Where do approval-agencies stand on these issues,” we wonder? Getting a device approved is tough and device manufacturers make the best effort, including a brand new battery to pass. But once rubber-stamped, the agencies wash their hands and places the responsibility of maintenance on to the user. Rules, especially with batteries, become vague and the user will ask: “At what capacity should I replace the battery? How much spare capacity is enough? How often should I test the battery, and what are early indications of pending battery failures?”
Agencies, such as the FDA, realize the lack of oversight on the battery for critical devices and have identified three problem areas they are trying to resolve:
Deficiency of quality assurance in batteries by device manufacturers
Lack of understanding in battery system integration
Not knowing the end of battery life
Batteries in the military also fail, and often without warning. A modern soldier carries radios, GPS devices, smartphones, night vision goggles, infrared sights, flashlights and counter-IED equipment. This amounts to roughly seven battery types, with 10 packs each for a 72-hour mission at a weight of about 9kg (20 lb) per solider. Reports indicate that batteries have become the second highest expense next to munitions. Without periodic performance checks, soldiers will carry rocks instead of batteries as Figure 1 demonstrates.
Figure 1: Soldier carries rocks instead of batteries.
Batteries fade with use and age. Each pack needs a periodic performance check to ease the weight carried by the combat solider.
Courtesy of Cadex
Other uses where the condition of a battery must be supervised are drones and robots. Drones are hard on the battery and the capacity fades quickly, reducing the flight time. As drones are used for many unique commercial applications, fleet maintenance cannot be limited to knowing the state-of-charge alone but also recording state-of-health, the energy storage capability based on capacity. Knowing the anticipated flight time will prevent an expensive vehicle from crashing on a longer than expected mission, struggling against headwind or attempting a second landing.
A battery should receive similar treatments as a critical part in an aircraft or a machine where wear and tear falls under strict maintenance guidelines. The service of a jet engine, for example, is measured in flight hours and flight cycles. One cycle includes a take-off and landing, and the Airbus 330 needs maintenance after 200-400 such cycles.
Such a procedure does not apply to the battery because accepted test norms have not been established. Auditors doing quality control shy away from such ruling and only examine the outer appearance; state-of-health is mostly ignored. This allows faded batteries to hide comfortably among their stronger peers. The battery holds special privileges and evades inspections. Should it quit during a critical mission, then this is seen as beyond control.
Most failures occurring during emergencies are caused by weak batteries as heavier than normal traffic depletes them prematurely. Capacity as a measure of performance evaluation and end of life indication is poorly understood. When asking a battery user: “At what capacity do you replace the battery?” most reply in confusion: “I beg your pardon?”
The leading health indicators in a battery are: [1] capacity that stores the energy, [2] internal resistance that enables current delivery, and [3] self-discharge that reflects the mechanical integrity and reveals stress-related damage. With average use, Li-ion provides 300 to 500 full discharge cycles before the capacity drops to about 80 percent, marking the end-of-life. Low capacity is the most common cause of failure; the capacity level also serves as benchmark when a battery should be replaced.
While improving battery performance is important – and the high attendance list at battery seminars proves this – not enough emphasis is placed on the battery once the pack enters active duty. Product development and agency approval are only pre-operational services alike the education of a youngster. While this is important to build a career, the workforce that follows is the proof of endurance. Batteries age and capacity-fade is as certain as death and taxes, a comment Benjamin Franklin made in 1789.
Battery diagnostics and monitoring have lagged behind other technologies but an industrial revolution in batteries is in the works. In the 1970s, the world had computers but little software. Bill Gates changed this with the PC and shared software. Today, the world evolves around batteries but lacks supervision as part of control technology. Future systems will assess battery performance during charge or by a rapid-test and make the results transparent to the battery user and fleet manager alike.
About the Author
Isidor Buchmann is the founder and CEO of Cadex Electronics Inc. For three decades, Buchmann has studied the behavior of rechargeable batteries in practical, everyday applications, has written award-winning articles including the best-selling book “Batteries in a Portable World,” now in its third edition. Cadex specializes in the design and manufacturing of battery chargers, analyzers and monitoring devices. For more information on batteries, visit www.batteryuniversity.com; product information is on www.cadex.com.
Last Updated: 23-Jun-2016
Batteries In A Portable World
The material on Battery University is based on the indispensable new 4th edition of "Batteries in a Portable World - A Handbook on Rechargeable Batteries for Non-Engineers" which is available for order through Amazon.com.
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Table of Contents
-
Introduction 4>
- BU-001: Sharing Battery Knowledge
- BU-002: Introduction
- BU-003: Dedication
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Crash Course on Batteries 4>
- BU-101: When Was the Battery Invented?
- BU-102: Early Innovators
- BU-103: Global Battery Markets
- BU-103a: Battery Breakthroughs: Myth or Fact?
- BU-104: Getting to Know the Battery
- BU-104a: Comparing the Battery with Other Power Sources
- BU-104b: Battery Building Blocks
- BU-104c: The Octagon Battery – What makes a Battery a Battery
- BU-105: Battery Definitions and what they mean
- BU-106: Advantages of Primary Batteries
- BU-106a: Choices of Primary Batteries
- BU-107: Comparison Table of Secondary Batteries
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Battery Types 4>
- BU-201: How does the Lead Acid Battery Work?
- BU-201a: Absorbent Glass Mat (AGM)
- BU-201b: Gel Lead Acid Battery
- BU-202: New Lead Acid Systems
- BU-203: Nickel-based Batteries
- BU-204: How do Lithium Batteries Work?
- BU-205: Types of Lithium-ion
- BU-206: Lithium-polymer: Substance or Hype?
- BU-208: Cycling Performance
- BU-209: How does a Supercapacitor Work?
- BU-210: How does the Fuel Cell Work?
- BU-210a: Why does Sodium-sulfur need to be heated
- BU-210b: How does the Flow Battery Work?
- BU-211: Alternate Battery Systems
- BU-212: Future Batteries
- BU-214: Summary Table of Lead-based Batteries
- BU-215: Summary Table of Nickel-based Batteries
- BU-216: Summary Table of Lithium-based Batteries
- BU-217: Summary Table of Alternate Batteries
- BU-218: Summary Table of Future Batteries
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Packaging and Safety 4>
- BU-301: A look at Old and New Battery Packaging
- BU-301a: Types of Battery Cells
- BU-302: Series and Parallel Battery Configurations
- BU-303: Confusion with Voltages
- BU-304: Why are Protection Circuits Needed?
- BU-304a: Safety Concerns with Li-ion
- BU-304b: Making Lithium-ion Safe
- BU-304c: Battery Safety in Public
- BU-305: Building a Lithium-ion Pack
- BU-306: What is the Function of the Separator?
- BU-307: How does Electrolyte Work?
- BU-308: Availability of Lithium
- BU-309: How does Graphite Work in Li-ion?
- BU-310: How does Cobalt Work in Li-ion?
- BU-311: Battery Raw Materials
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Charge Methods 4>
- BU-401: How do Battery Chargers Work?
- BU-401a: Fast and Ultra-fast Chargers
- BU-402: What Is C-rate?
- BU-403: Charging Lead Acid
- BU-404: What is Equalizing Charge?
- BU-405: Charging with a Power Supply
- BU-406: Battery as a Buffer
- BU-407: Charging Nickel-cadmium
- BU-408: Charging Nickel-metal-hydride
- BU-409: Charging Lithium-ion
- BU-409a: Why do Old Li-ion Batteries Take Long to Charge?
- BU-409b: Charging Lithium Iron Phosphate
- BU-410: Charging at High and Low Temperatures
- BU-411: Charging from a USB Port
- BU-412: Charging without Wires
- BU-413: Charging with Solar, Turbine
- BU-413a: How to Store Renewable Energy in a Battery
- BU-414: How do Charger Chips Work?
- BU-415: How to Charge and When to Charge?
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Discharge Methods 4>
- BU-501: Basics about Discharging
- BU-501a: Discharge Characteristics of Li-ion
- BU-502: Discharging at High and Low Temperatures
- BU-503: Determining Power Deliver by the Ragone Plot
- BU-504: How to Verify Sufficient Battery Capacity
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"Smart" Battery 4>
- BU-601: How does a Smart Battery Work?
- BU-602: How does a Battery Fuel Gauge Work?
- BU-603: How to Calibrate a “Smart” Battery
- BU-603a: Calibrating SMBus Batteries with Impedance Tracking
- BU-604: How to Process Data from a “Smart” Battery
- Testing and Calibrating Smart Batteries
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From Birth to Retirement 4>
- BU-701: How to Prime Batteries
- BU-702: How to Store Batteries
- BU-703: Health Concerns with Batteries
- BU-704: How to Transport Batteries
- BU-704a: Shipping Lithium-based Batteries by Air
- BU-704b: CAUTION & Overpack Labels
- BU-704c: Class 9 Label
- BU-704d: NFPA 704 Rating
- BU-704e: Battery for Personal and Fleet Use
- BU-705: How to Recycle Batteries
- BU-705a: Battery Recycling as a Business
- BU-706: Summary of Do's and Don'ts
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How To Prolong Battery Life 4>
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General 4>
- BU-801: Setting Battery Performance Standards
- BU-801a: How to Rate Battery Runtime
- BU-801b: How to Define Battery Life
- BU-802: What Causes Capacity Loss?
- BU-802a: How does Rising Internal Resistance affect Performance?
- BU-802b: What does Elevated Self-discharge Do?
- BU-802c: How Low can a Battery be Discharged?
- BU-803: Can Batteries Be Restored?
- BU-803a: Cell Matching and Balancing
- BU-803b: What causes Cells to Short?
- BU-803c: Loss of Electrolyte
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Lead Acid 4>
- BU-804: How to Prolong Lead-acid Batteries
- BU-804a: Corrosion, Shedding and Internal Short
- BU-804b: Sulfation and How to Prevent it
- BU-804c: Acid Stratification and Surface Charge
- BU-805: Additives to Boost Flooded Lead Acid
- BU-806: Tracking Battery Capacity and Resistance as part of Aging
- BU-806a: How Heat and Loading affect Battery Life
-
Nickel-based 4>
- BU-807: How to Restore Nickel-based Batteries
- BU-807a: Effect of Zapping
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Lithium-ion 4>
- BU-808: How to Prolong Lithium-based Batteries
- BU-808a: How to Awaken a Sleeping Li-ion
- BU-808b: What Causes Li-ion to Die?
- BU-808c: Coulombic and Energy Efficiency with the Battery
- BU-809: How to Maximize Runtime
- BU-810: What Everyone Should Know About Aftermarket Batteries
- BU-811: Assuring Minimum Operational Reserve Energy (MORE)
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Battery Testing and Monitoring 4>
- BU-901: Fundamentals in Battery Testing
- BU-901b: How to Measure the Remaining Useful Life of a Battery
- BU-902: How to Measure Internal Resistance
- BU-902a: How to Measure CCA
- BU-903: How to Measure State-of-charge
- BU-904: How to Measure Capacity
- BU-905: Testing Lead Acid Batteries
- BU-905a: Testing Starter Batteries in Vehicles
- BU-905b: Knowing when to Replace a Starter Battery
- BU-906: Testing Nickel-based Batteries
- BU-907: Testing Lithium-based Batteries
- BU-907a: Battery Rapid-test Methods
- BU-907b: Advancements in Battery Testing
- BU-907c: Cloud Analytics in Batteries
- BU-908: Battery Management System (BMS)
- BU-909: Battery Test Equipment
- BU-910: How to Repair a Battery Pack
- BU-911: How to Repair a Laptop Battery
- BU-915: Testing Battery with EIS
- BU-916: Deep Battery Diagnostics
- BU-917: In Search for Performance Transparency with Batteries
- BU-918: Battery Endurance Plan
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Amazing Value of a Battery 4>
- BU-1001: Batteries in Industries
- BU-1002: Electric Powertrain, then and now
- BU-1002a: Hybrid Electric Vehicles and the Battery
- BU-1002b: Environmental Benefit of the Electric Powertrain
- BU-1003: Electric Vehicle (EV)
- BU-1003a: Battery Aging in an Electric Vehicle (EV)
- BU-1004: Charging an Electric Vehicle
- BU-1005: Does the Fuel Cell-powered Vehicle have a Future?
- BU-1006: Cost of Mobile and Renewable Power
- BU-1007: Net Calorific Value
- BU-1008: Working towards Sustainability
- BU-1009: Battery Paradox - Afterword
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Information 4>
- BU-1101: Glossary
- BU-1102: Abbreviations
- BU-1103: Bibliography
- BU-1104: About the Author
- BU-1105: About Cadex (Sponsor)
- BU-1106: Author's Creed
- BU-1107: Disclaimer
- BU-1108: Copyright
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Learning Tools 4>
- BU-1501 Battery History
- BU-1502 Basics about Batteries
- BU-1503 How to Maintain Batteries
- BU-1504 Battery Test & Analyzing Devices
- BU-1505 Short History of Cadex
-
Battery Articles 4>
- Perception of a Battery Tester
- Green Deal
- Risk Management in Batteries
- Predictive Test Methods for Starter Batteries
- Why Mobile Phone Batteries do not last as long as an EV Battery
- Battery Rapid-test Methods
- How to Charge Li-ion with a Parasitic Load
- Ultra-fast Charging
- Assuring Safety of Lithium-ion in the Workforce
- Diagnostic Battery Management
- Tweaking the Mobile Phone Battery
- Battery Test Methods
- Battery Testing and Safety
- How to Make Battery Performance Transparent
- Battery Diagnostics On-the-fly
- Making Battery State-of-health Transparent
- Batteries will eventually die, but when and how?
- Why does Pokémon Go rob so much Battery Power?
- How to Care for the Battery
- Tesla’s iPhone Moment — How the Powerwall will Change Global Energy Use
- Painting the Battery Green by giving it a Second Life
- Charging without Wires — A Solution or Laziness
- What everyone should know about Battery Chargers
- A Look at Cell Formats and how to Build a good Battery
- Battery Breakthroughs — Myth or Fact?
- Rapid-test Methods that No Longer Work
- Shipping Lithium-based Batteries by Air
- How to make Batteries more Reliable and Longer Lasting
- What causes Lithium-ion to die?
- Safety of Lithium-ion Batteries
- Recognizing Battery Capacity as the Missing Link
- Managing Batteries for Warehouse Logistics
- Caring for your Starter Battery
- Giving Batteries a Second Life
- How to Make Batteries in Medical Devices More Reliable
- Possible Solutions for the Battery Problem on the Boeing 787
- Impedance Spectroscopy Checks Battery Capacity in 15 Seconds
- How to Improve the Battery Fuel Gauge
- Examining Loading Characteristics on Primary and Secondary Batteries
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Language Pool 4>
- BU-001: Compartir conocimiento sobre baterías
- BU-002: Introducción
- BU-003: Dedicatoria
- BU-104: Conociendo la Batería
- BU-302: Configuraciones de Baterías en Serie y Paralelo
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Batteries in a Portable World book 4>
- Change-log of “Batteries in a Portable World,” 4th edition: Chapters 1 - 3
- Change-log of “Batteries in a Portable World,” 4th edition: Chapters 4 - 10