BU-305: Building a Lithium-ion Pack
Building a Li-ion battery pack begins by satisfying voltage and runtime requirements, and then taking loading, environmental, size and weight limitations into account. Portable designs for consumer products want a slim profile and the choice is a prismatic or pouch cell. If space allows, a cylindrical cell such as the 18650 often provides the lowest cost and best performance in terms of specific energy, safety and durability. (See BU-301a: Types of Battery Cells)
Most battery packs for medical devices, power tools, e-bikes and even powertrains for electric cars (EV) are based on the 18650. This appears impractical but the small cell works well because it is one of the most mature Li-ion formats available, is produced in high volume and enjoys a low cost per Wh.
The cylindrical cell is not ideal as it leaves empty spaces in a mul ti-cell configuration. This disadvantage turns into an advantage when considering flexibility and cooling. The Tesla S85 EV uses over 7,000 cells, switched in parallel to boost the current and in series to increase the voltage. Should one cell in series open, the total power loss is minimal; if one in parallel shorts, fuse protection removes this cell from the circuit. Failing cells can thus be eliminated without bringing the battery down.
EV manufacturers are not united on the choice of cell, but there is a trend towards larger formats to reduce supportive electronics that adds 20–25 percent to the finished pack. With a larger cell, however, the electronic components get dearer because of higher current handling. According to 2015 reports, the Tesla S 85 has the lowest cost per kWh using the 18650. Other EVs have larger prismatic cells at higher kWh costs. Table 1 compares the kWh cost.
Make and model | Cell type | Cost per kWh | Specific energy |
Tesla S 85, 90kWh (2015)* | 18650 | $260/kWh | 250Wh/kg |
Tesla 48kWh Gen III | 18650 | $260/kWh | 250Wh/kg |
Best practices DoE/AABC) | pouch/prismatic | $350/kWh | 150–180Wh/kg |
Nissan Leaf, 30kWh (2016)* | pouch/prismatic | $455/kWh | 80–96Wh/kg |
BMW i3 | pouch/prismatic | N/A | 120Wh/kg |
Table 1: Price comparison of EV batteries.
Mass production allows a low price using the 18650 cell.
* In 2015/16 Tesla S 85 increased the battery from 85kWh to 90kWh; Nissan Leaf from 25kWh to 30kWh.
Batteries should be designed to permit failure without a catastrophic event. All energy sources will fail eventually and the battery is no exception. After an unwanted event, the FAA mandated to place the Li-ion ship-battery of the Boeing Dreamliner 787 into a metal container with venting to the outside. Tesla reinforced the EV battery by adding a heavy-gauge steel plate on the bottom that provides extra protection against projectiles from the road.
Large batteries for power applications are cooled. Some use a rod system to bring the heat to the outside, others deploy forced air or use liquid cooling. Liquid cooling is superior and although more expensive, EV batteries gravitate towards this form of cooling.
Meeting Safety Approvals
Reputable battery manufacturers do not supply Li-ion cells to uncertified battery assemblers. This precaution is understandable, considering that Li-ion cells could be charged and discharged beyond safe limits with inadequate protection circuits.
Authorizing a battery pack for the commercial market and for air transport can cost $10,000 to $20,000. Such a high price is troubling, knowing that cell manufacturers discontinue older cells in favor of higher capacity replacements. A pack with the new cell, even if specified as a direct replacement, requires new certifications.
The common question asked is, “Why are additional tests needed when the cells are already approved?” The simple answer is that cell approvals cannot be transferred to the pack because regulatory authorities place the safety confirmation on a finished product and not the components. The completed battery must be tested and registered to assure correct assembly and compliance with safety standards.
As part of the test requirements, the finished battery must undergo electrical and mechanical assessment to meet the Recommendations on the Transport of Dangerous Goods on lithium-ion batteries for air shipment, rules set by the United Nations (UN). The UN Transportation Testing (UN/DOT 38.3) works in conjunction with the Federal Aviation Administration (FAA), the US Department of Transport (US DOT) and the International Air Transport Association (IATA)*. The certification applies to primary and secondary lithium-based cells.
The UN 38.3 test includes:
T1 – Altitude Simulation: Low pressure simulates unpressurized cargo hold at 15,000 meters.
T2 – Thermal Test: Temperature extreme by keeping batteries for 6h at -40°C and then +75°C.
T3 – Vibration: Simulates vibration during transportation at 7Hz to 200Hz for up to 3 hours.
T4 – Shock: Simulates vibration during transportation at given G-forces relating to battery size.
T5 – External Short Circuit: Short circuit with <0.1Ω at 50°C. Case cannot exceed 170°C.
T6 – Impact: >20mm cylindrical cells are impact tested; <20mm cell types are crush tested.
T7 – Overcharge: Charge at twice the recommended current for 24 hours (secondary batteries only)
T8 – Forced Discharge: Same as T7, forced discharge with primary and secondary cells.
The test batteries must pass the tests without causing harm, but the packs do not need to function thereafter. The test is strictly for safety and not consumer endurance. The authorized laboratory needs 24 battery samples consisting of 12 new packs and 12 specimens that have been cycled 50 times. IATA wants to ensure that the batteries in question are airworthy and have field integrity; cycling the packs 50 times before the test satisfies this requirement.
The high certification cost discourages small manufacturers from using Li-ion for low-volume products and entrepreneurs may choose nickel-based systems instead. These batteries do not need to be tested to the level of lithium-based products for air transport. While reputable companies follow the instructions, rules are being broken and the penalties are stiff. ( See BU-704: How to Transport Batteries)
Simple Guidelines for Using Lithium-ion Batteries
Exercise caution when handling and testing lithium-ion batteries.
Do not short-circuit, overcharge, crush, drop, mutilate, penetrate with foreign objects, apply reverse polarity, expose to high temperature or disassemble packs and cells.
Use only lithium-ion batteries with a designated protection circuit and approved charger.
Discontinue using a battery and/or charger if the pack temperature rises more than 10ºC (18ºF) on a regular charge.
The electrolyte is highly flammable and battery rupture can cause physical injury.
* IATA (International Air Transport Association) works with airlines and the air transport industry to promote safe, reliable, secure and economical air travel.
Last Updated: 25-Oct-2021
Batteries In A Portable World
The material on Battery University is based on the indispensable new 4th edition of "Batteries in a Portable World - A Handbook on Rechargeable Batteries for Non-Engineers" which is available for order through Amazon.com.
Find An Article
Table of Contents
-
Introduction 4>
- BU-001: Sharing Battery Knowledge
- BU-002: Introduction
- BU-003: Dedication
-
Crash Course on Batteries 4>
- BU-101: When Was the Battery Invented?
- BU-102: Early Innovators
- BU-103: Global Battery Markets
- BU-103a: Battery Breakthroughs: Myth or Fact?
- BU-104: Getting to Know the Battery
- BU-104a: Comparing the Battery with Other Power Sources
- BU-104b: Battery Building Blocks
- BU-104c: The Octagon Battery – What makes a Battery a Battery
- BU-105: Battery Definitions and what they mean
- BU-106: Advantages of Primary Batteries
- BU-106a: Choices of Primary Batteries
- BU-107: Comparison Table of Secondary Batteries
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Battery Types 4>
- BU-201: How does the Lead Acid Battery Work?
- BU-201a: Absorbent Glass Mat (AGM)
- BU-201b: Gel Lead Acid Battery
- BU-202: New Lead Acid Systems
- BU-203: Nickel-based Batteries
- BU-204: How do Lithium Batteries Work?
- BU-205: Types of Lithium-ion
- BU-206: Lithium-polymer: Substance or Hype?
- BU-208: Cycling Performance
- BU-209: How does a Supercapacitor Work?
- BU-210: How does the Fuel Cell Work?
- BU-210a: Why does Sodium-sulfur need to be heated
- BU-210b: How does the Flow Battery Work?
- BU-211: Alternate Battery Systems
- BU-212: Future Batteries
- BU-214: Summary Table of Lead-based Batteries
- BU-215: Summary Table of Nickel-based Batteries
- BU-216: Summary Table of Lithium-based Batteries
- BU-217: Summary Table of Alternate Batteries
- BU-218: Summary Table of Future Batteries
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Packaging and Safety 4>
- BU-301: A look at Old and New Battery Packaging
- BU-301a: Types of Battery Cells
- BU-302: Series and Parallel Battery Configurations
- BU-303: Confusion with Voltages
- BU-304: Why are Protection Circuits Needed?
- BU-304a: Safety Concerns with Li-ion
- BU-304b: Making Lithium-ion Safe
- BU-304c: Battery Safety in Public
- BU-305: Building a Lithium-ion Pack
- BU-306: What is the Function of the Separator?
- BU-307: How does Electrolyte Work?
- BU-308: Availability of Lithium
- BU-309: How does Graphite Work in Li-ion?
- BU-310: How does Cobalt Work in Li-ion?
- BU-311: Battery Raw Materials
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Charge Methods 4>
- BU-401: How do Battery Chargers Work?
- BU-401a: Fast and Ultra-fast Chargers
- BU-402: What Is C-rate?
- BU-403: Charging Lead Acid
- BU-404: What is Equalizing Charge?
- BU-405: Charging with a Power Supply
- BU-406: Battery as a Buffer
- BU-407: Charging Nickel-cadmium
- BU-408: Charging Nickel-metal-hydride
- BU-409: Charging Lithium-ion
- BU-409a: Why do Old Li-ion Batteries Take Long to Charge?
- BU-409b: Charging Lithium Iron Phosphate
- BU-410: Charging at High and Low Temperatures
- BU-411: Charging from a USB Port
- BU-412: Charging without Wires
- BU-413: Charging with Solar, Turbine
- BU-413a: How to Store Renewable Energy in a Battery
- BU-414: How do Charger Chips Work?
- BU-415: How to Charge and When to Charge?
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Discharge Methods 4>
- BU-501: Basics about Discharging
- BU-501a: Discharge Characteristics of Li-ion
- BU-502: Discharging at High and Low Temperatures
- BU-503: Determining Power Deliver by the Ragone Plot
- BU-504: How to Verify Sufficient Battery Capacity
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"Smart" Battery 4>
- BU-601: How does a Smart Battery Work?
- BU-602: How does a Battery Fuel Gauge Work?
- BU-603: How to Calibrate a “Smart” Battery
- BU-603a: Calibrating SMBus Batteries with Impedance Tracking
- BU-604: How to Process Data from a “Smart” Battery
- Testing and Calibrating Smart Batteries
-
From Birth to Retirement 4>
- BU-701: How to Prime Batteries
- BU-702: How to Store Batteries
- BU-703: Health Concerns with Batteries
- BU-704: How to Transport Batteries
- BU-704a: Shipping Lithium-based Batteries by Air
- BU-704b: CAUTION & Overpack Labels
- BU-704c: Class 9 Label
- BU-704d: NFPA 704 Rating
- BU-704e: Battery for Personal and Fleet Use
- BU-705: How to Recycle Batteries
- BU-705a: Battery Recycling as a Business
- BU-706: Summary of Do's and Don'ts
-
How To Prolong Battery Life 4>
-
General 4>
- BU-801: Setting Battery Performance Standards
- BU-801a: How to Rate Battery Runtime
- BU-801b: How to Define Battery Life
- BU-802: What Causes Capacity Loss?
- BU-802a: How does Rising Internal Resistance affect Performance?
- BU-802b: What does Elevated Self-discharge Do?
- BU-802c: How Low can a Battery be Discharged?
- BU-803: Can Batteries Be Restored?
- BU-803a: Cell Matching and Balancing
- BU-803b: What causes Cells to Short?
- BU-803c: Loss of Electrolyte
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Lead Acid 4>
- BU-804: How to Prolong Lead-acid Batteries
- BU-804a: Corrosion, Shedding and Internal Short
- BU-804b: Sulfation and How to Prevent it
- BU-804c: Acid Stratification and Surface Charge
- BU-805: Additives to Boost Flooded Lead Acid
- BU-806: Tracking Battery Capacity and Resistance as part of Aging
- BU-806a: How Heat and Loading affect Battery Life
-
Nickel-based 4>
- BU-807: How to Restore Nickel-based Batteries
- BU-807a: Effect of Zapping
-
Lithium-ion 4>
- BU-808: How to Prolong Lithium-based Batteries
- BU-808a: How to Awaken a Sleeping Li-ion
- BU-808b: What Causes Li-ion to Die?
- BU-808c: Coulombic and Energy Efficiency with the Battery
- BU-809: How to Maximize Runtime
- BU-810: What Everyone Should Know About Aftermarket Batteries
- BU-811: Assuring Minimum Operational Reserve Energy (MORE)
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Battery Testing and Monitoring 4>
- BU-901: Fundamentals in Battery Testing
- BU-901b: How to Measure the Remaining Useful Life of a Battery
- BU-902: How to Measure Internal Resistance
- BU-902a: How to Measure CCA
- BU-903: How to Measure State-of-charge
- BU-904: How to Measure Capacity
- BU-905: Testing Lead Acid Batteries
- BU-905a: Testing Starter Batteries in Vehicles
- BU-905b: Knowing when to Replace a Starter Battery
- BU-906: Testing Nickel-based Batteries
- BU-907: Testing Lithium-based Batteries
- BU-907a: Battery Rapid-test Methods
- BU-907b: Advancements in Battery Testing
- BU-907c: Cloud Analytics in Batteries
- BU-908: Battery Management System (BMS)
- BU-909: Battery Test Equipment
- BU-910: How to Repair a Battery Pack
- BU-911: How to Repair a Laptop Battery
- BU-915: Testing Battery with EIS
- BU-916: Deep Battery Diagnostics
- BU-917: In Search for Performance Transparency with Batteries
- BU-918: Battery Endurance Plan
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Amazing Value of a Battery 4>
- BU-1001: Batteries in Industries
- BU-1002: Electric Powertrain, then and now
- BU-1002a: Hybrid Electric Vehicles and the Battery
- BU-1002b: Environmental Benefit of the Electric Powertrain
- BU-1003: Electric Vehicle (EV)
- BU-1003a: Battery Aging in an Electric Vehicle (EV)
- BU-1004: Charging an Electric Vehicle
- BU-1005: Does the Fuel Cell-powered Vehicle have a Future?
- BU-1006: Cost of Mobile and Renewable Power
- BU-1007: Net Calorific Value
- BU-1008: Working towards Sustainability
- BU-1009: Battery Paradox - Afterword
-
Information 4>
- BU-1101: Glossary
- BU-1102: Abbreviations
- BU-1103: Bibliography
- BU-1104: About the Author
- BU-1105: About Cadex (Sponsor)
- BU-1106: Author's Creed
- BU-1107: Disclaimer
- BU-1108: Copyright
-
Learning Tools 4>
- BU-1501 Battery History
- BU-1502 Basics about Batteries
- BU-1503 How to Maintain Batteries
- BU-1504 Battery Test & Analyzing Devices
- BU-1505 Short History of Cadex
-
Battery Articles 4>
- Perception of a Battery Tester
- Green Deal
- Risk Management in Batteries
- Predictive Test Methods for Starter Batteries
- Why Mobile Phone Batteries do not last as long as an EV Battery
- Battery Rapid-test Methods
- How to Charge Li-ion with a Parasitic Load
- Ultra-fast Charging
- Assuring Safety of Lithium-ion in the Workforce
- Diagnostic Battery Management
- Tweaking the Mobile Phone Battery
- Battery Test Methods
- Battery Testing and Safety
- How to Make Battery Performance Transparent
- Battery Diagnostics On-the-fly
- Making Battery State-of-health Transparent
- Batteries will eventually die, but when and how?
- Why does Pokémon Go rob so much Battery Power?
- How to Care for the Battery
- Tesla’s iPhone Moment — How the Powerwall will Change Global Energy Use
- Painting the Battery Green by giving it a Second Life
- Charging without Wires — A Solution or Laziness
- What everyone should know about Battery Chargers
- A Look at Cell Formats and how to Build a good Battery
- Battery Breakthroughs — Myth or Fact?
- Rapid-test Methods that No Longer Work
- Shipping Lithium-based Batteries by Air
- How to make Batteries more Reliable and Longer Lasting
- What causes Lithium-ion to die?
- Safety of Lithium-ion Batteries
- Recognizing Battery Capacity as the Missing Link
- Managing Batteries for Warehouse Logistics
- Caring for your Starter Battery
- Giving Batteries a Second Life
- How to Make Batteries in Medical Devices More Reliable
- Possible Solutions for the Battery Problem on the Boeing 787
- Impedance Spectroscopy Checks Battery Capacity in 15 Seconds
- How to Improve the Battery Fuel Gauge
- Examining Loading Characteristics on Primary and Secondary Batteries
-
Language Pool 4>
- BU-001: Compartir conocimiento sobre baterías
- BU-002: Introducción
- BU-003: Dedicatoria
- BU-104: Conociendo la Batería
- BU-302: Configuraciones de Baterías en Serie y Paralelo
-
Batteries in a Portable World book 4>
- Change-log of “Batteries in a Portable World,” 4th edition: Chapters 1 - 3
- Change-log of “Batteries in a Portable World,” 4th edition: Chapters 4 - 10