Batteries against Fossil Fuel
NOTE: This article has been archived. Please read our new "Cost of Power" for an updated version.
Lifting off in a large airplane is always exhilarating. At a full weight of almost 400 tons, the Boeing 747 requires 90 megawatts of power to get airborne. Takeoff is the most demanding part of the journey, and when the plane reaches cruising altitude the power consumption decreases to half.
Powerful engines were used also when the mighty Queen Mary was launched in 1934. The 81,000-ton ocean liner measuring 300 meters (1,000ft) in length was propelled by four steam turbines producing a total power of 160,000hp (120 megawatts). While in service, the ship carried 3,000 souls and traveled at a speed of 28.5 knots (52km/h). The Queen Mary is now retired in Long Beach, California.
Large propulsion systems are only practical with internal combustion engines, and fossil fuel serves as a cheap and readily available power source. Low energy-to-weight ratio in terms of net calorific value (NCV), as well as a relatively short life span, makes batteries unsuitable beyond a given application. While fossil fuel delivers a NCV of 12,000Wh/kg, a manganese type lithium-ion battery offers 120Wh/kg, which is one hundred times less per weight. Even at a low efficiency of 25 percent, the internal combustion engine outperforms the best battery in terms of energy-to-weight ratio. The capacity of a battery would need to increase twenty-fold before it could compete head-to-head with fossil fuel.
Another limitation of battery propulsion over fossil fuel is the fuel by weight. While the weight diminishes as it is being consumed, the battery has the same deadweight whether fully charged or empty. This puts limitations on EV driving distance and would make the electric airplane impractical. Furthermore, the combustion engine delivers full power at freezing temperatures and continues to perform well with advancing age, a trait that is not achievable with the battery. A battery that is a few years old may deliver only half of the rated capacity.
Power from Primary Batteries
Energy from non-rechargeable batteries is most expensive in terms of cost per kilowatt-hours (kWh). Primary batteries are used for low-power applications such as wristwatches, remote controls, electric keys and children’s toys. Military in combat, light beacons and remote repeater stations also use primaries because charging is not practical. Table 1 estimates the storage capability and cost per kWh of primary batteries.
| AAA Cell | AA Cell | C Cell | D Cell | 9 Volt |
Capacity (alkaline) | 1,100mAh | 2,500mAh | 7,000mAh | 14,000mAh | 600mAh |
Energy (single cell) | 1.4Wh | 3Wh | 9Wh | 18Wh | 4.2Wh |
Cost per cell (US$) | $1.25 | $1.00 | $1.60 | $1.60 | $3.10 |
Cost per kWh (US$) | $890 | $330 | $180 | $90 | $730 |
Table 1: Energy and cost comparison of primary alkaline cells. Energy from primary batteries is most expensive; cost increases with smaller battery sizes.
Power from Secondary Batteries
Improved runtimes, lower unit price and the convenience of recharging have shifted many portable applications previously reserved for primary batteries to rechargeable batteries. Table 2 compares the cost of power with rechargeable batteries. The cost is based on battery price and the number of possible discharge/charge cycles. The analysis does not include electricity for charging or the cost of purchasing and maintaining charging equipment. The table compares commercial battery packs used for communications, computing or medical devices.
| Lead Acid | NiCd | NiMH | Li‑ion |
Capacity | 2,000mAh | 600mAh | 1,000mAh | 1,200mAh |
Battery voltage | 12V | 7.2V | 7.2V | 7.2V |
Energy per cycle | 24Wh | 4.5Wh | 7.5Wh | 8.6Wh |
Number of cycles | 250 | 1,000* | 500 | 500 |
Battery cost (est.) | $50 | $50 | $70 | $100 |
Cost per kWh ($US) | $8.50 | $11.00 | $18.50 | $24.00 |
Table 2: Energy and cost comparison using rechargeable batteries. Older technologies have lower cost/kWh than newer systems; larger cells are most cost-effective. The costs are commercial packs at estimated over-the-counter prices.
* Cycle life is based on battery receiving maintenance.
Power from Other Sources
With dwindling fossil fuel supply, governments and the private sector are studying alternate energies. Table 3 compares the cost to generate 1kW of power by taking into account the initial investment, adding the consumption of fuel and including the eventual replacement of the system. Power from the electrical utility grid is most cost-effective; consumers in industrialized countries pay between $0.05 and $0.25US per kWh. (The typical daily energy consumption per household is 25kW.) Gasoline (and equivalent) is the most economical portable fuel.
Fuel type | Equipment | Life span | Cost of fuel | Total cost |
Li-ion | $1,000/kW | 2,500h (replacement cost $0.40/kW) | $0.10 | $0.50 |
Gasoline engine for vehicular use | $30/kW | 4,000h | $0.33 | $0.34 |
Fuel cell | $3,000 – 7,500 |
| $0.35 |
|
Electricity | All inclusive | All inclusive | $0.10 | $0.10 |
Table 3: Cost of generating 1kW of energy
The table includes the initial investment, fuel consumption, maintenance and eventual replacement of the equipment. The figures are estimates at the time of writing.
The fuel cell is most effective in converting fuel to electricity, but high equipment cost makes this power source expensive in terms of cost per kWh. In virtually all applications, power from the fuel cell is considerably more expensive than from conventional methods.
We now look at the energy that our bodies consume. An active man requires 3,500 calories per day to stay fit, which relates to roughly 4,000 watts in a 24-hour day (1 food calorie = 1.16 watt-hour). Traveling on foot covers about 40km (25 miles) per day and a bicycle increases the distance by a factor of four to 160km (100 miles). Eating two potatoes and a sausage for lunch can propel a bicyclist for the entire afternoon, covering 40km (25 miles), as I have experienced myself. The human body is amazingly efficient in converting food to energy.
Table 4 compares the energy per passenger/kilometer for a loaded Boeing 747, the retired Queen Mary ocean liner, a gas-guzzling SUV, a fit person on a bicycle, and a person walking on foot. The figures are estimated.
| Boeing 747 | Ocean liner Queen Marry | SUV | Bicycle | On foot |
Weight (loaded) | 369 tons | 81,000 tons | 2.5 tons | 100kg (220lb) | 80kg |
Cruising speed | 900km/h | 52km/h | 100km/h | 20km/h | 5km/h |
Maximum power | 77,000kW | 120,000kW | 200kW | 2,000W | 2,000W |
Power at cruising | 65,000kW | 90,000 kW | 130 kW | 80 W | 280 W |
Passenger | 450 | 3000 | 4 | 1 | 1 |
Power per passenger | 140kW | 40kW | 50kW | 80W | 280W |
Energy per passenger | 580 kilojoules* | 2,800 kilojoules* | 1,800 kilojoules* | 14.4 kilojoules* | 200 kilojoules* |
Table 4: Power needs of different transportation modes. In terms of high-speed transportation, air travel consumes theleast amount of energy per passenger-km. The boat is efficient for slow and heavy freight. The absolute lowest energy consumption is the bicycle.
* 1 joule is the energy of 1A at 1V for 1 second, or 1 watt/s, or 0.238 calorie/s; 4.186 joules raise the temperature of 1g of water by 1°Celsius; 1,000 joules are 0.277Wh.
Bicycles are by far the most effective form of transportation. Comparing the energy consumption of a bicycle to that of a car, a cyclist would consume only 0.4 liter of fuel per 100km (630mpg). Walking is also efficient; it uses about one liter per 100km (228mpg). The problem with self-powered propulsion is the limited travel range before fatigue sets in.
In terms of energy usage, cars are one of the least efficient modes of transportation. The internal combustion engine utilizes only 25 percent of the net calorific value from the fuel for propulsion. The calculation looks even worse when taking into account the weight of the vehicle with a single passenger, the driver. The ratio of machine to man is typically ten-to-one. When accelerating a 1.5-ton vehicle, less than two percent of the energy moves the 75kg (165lb) driver, his briefcase and the lunch bag; 98 percent goes to heat and friction. Even a modern jet plane has better fuel efficiency than a car. A fully occupied Airbus 340 gets 3.4l/100km (70mpg), cruising at 950km/h (594mph).
Trains are one of the most efficient modes of transportation. The 36km Yamanote circle line connecting major urban centers in Tokyo carries 3.5 million passengers per day. During rush hour, the 11-car train runs every 150 seconds. Such a passenger volume would be unthinkable by private cars on city streets. Trains are also economical to move freight. Transporting one ton of freight consumes only 0.65 liters of fuel per 100km (362mpg).
Affluent societies want personal transportation, but with a large critical mass driving vehicles on government-funded highways with minimal contribution by the drivers and without mandated limits, this free-roaming lifestyle is taking a toll on our energy resources. Developing countries also desire personal transportation. As car become affordable to them, they will begin consuming fossil fuel too and this will increase the need for hydrocarbons further. According to the US Department of Energy, 71 percent of the oil consumed in the USA is for transportation. Out of this, 51 percent goes to passenger cars and light trucks. Smaller vehicles and the development of efficient rail systems could cut the energy for transportation in half. Read more about Free energy... Almost!
Alternate Fuels for Transportation
Governments are exploring ways to reduce the dependency on fossil fuel and to lower emissions. They do this by promoting the electric car. This is done in good faith, but looking at Figure 5 we may be facing an impossible task. Many readers will agree that the success of personal transportation was only made possible with the abundance of oil at very low price in terms of net calorific value. The notion of driving a large vehicle for long distances may not be transferable with battery propulsion, even with government subsidies. Today’s batteries are weak contenders against petroleum, and the chart below demonstrates this. Li-ion, the battery choice for the electric vehicle, is hardly visible; the 90 percent efficiency of the electric motor does not make up for the low net calorific value.
Last Updated: 5-Jul-2016
Batteries In A Portable World
The material on Battery University is based on the indispensable new 4th edition of "Batteries in a Portable World - A Handbook on Rechargeable Batteries for Non-Engineers" which is available for order through Amazon.com.
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Table of Contents
-
Introduction 4>
- BU-001: Sharing Battery Knowledge
- BU-002: Introduction
- BU-003: Dedication
-
Crash Course on Batteries 4>
- BU-101: When Was the Battery Invented?
- BU-102: Early Innovators
- BU-103: Global Battery Markets
- BU-103a: Battery Breakthroughs: Myth or Fact?
- BU-104: Getting to Know the Battery
- BU-104a: Comparing the Battery with Other Power Sources
- BU-104b: Battery Building Blocks
- BU-104c: The Octagon Battery – What makes a Battery a Battery
- BU-105: Battery Definitions and what they mean
- BU-106: Advantages of Primary Batteries
- BU-106a: Choices of Primary Batteries
- BU-107: Comparison Table of Secondary Batteries
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Battery Types 4>
- BU-201: How does the Lead Acid Battery Work?
- BU-201a: Absorbent Glass Mat (AGM)
- BU-201b: Gel Lead Acid Battery
- BU-202: New Lead Acid Systems
- BU-203: Nickel-based Batteries
- BU-204: How do Lithium Batteries Work?
- BU-205: Types of Lithium-ion
- BU-206: Lithium-polymer: Substance or Hype?
- BU-208: Cycling Performance
- BU-209: How does a Supercapacitor Work?
- BU-210: How does the Fuel Cell Work?
- BU-210a: Why does Sodium-sulfur need to be heated
- BU-210b: How does the Flow Battery Work?
- BU-211: Alternate Battery Systems
- BU-212: Future Batteries
- BU-214: Summary Table of Lead-based Batteries
- BU-215: Summary Table of Nickel-based Batteries
- BU-216: Summary Table of Lithium-based Batteries
- BU-217: Summary Table of Alternate Batteries
- BU-218: Summary Table of Future Batteries
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Packaging and Safety 4>
- BU-301: A look at Old and New Battery Packaging
- BU-301a: Types of Battery Cells
- BU-302: Series and Parallel Battery Configurations
- BU-303: Confusion with Voltages
- BU-304: Why are Protection Circuits Needed?
- BU-304a: Safety Concerns with Li-ion
- BU-304b: Making Lithium-ion Safe
- BU-304c: Battery Safety in Public
- BU-305: Building a Lithium-ion Pack
- BU-306: What is the Function of the Separator?
- BU-307: How does Electrolyte Work?
- BU-308: Availability of Lithium
- BU-309: How does Graphite Work in Li-ion?
- BU-310: How does Cobalt Work in Li-ion?
- BU-311: Battery Raw Materials
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Charge Methods 4>
- BU-401: How do Battery Chargers Work?
- BU-401a: Fast and Ultra-fast Chargers
- BU-402: What Is C-rate?
- BU-403: Charging Lead Acid
- BU-404: What is Equalizing Charge?
- BU-405: Charging with a Power Supply
- BU-406: Battery as a Buffer
- BU-407: Charging Nickel-cadmium
- BU-408: Charging Nickel-metal-hydride
- BU-409: Charging Lithium-ion
- BU-409a: Why do Old Li-ion Batteries Take Long to Charge?
- BU-409b: Charging Lithium Iron Phosphate
- BU-410: Charging at High and Low Temperatures
- BU-411: Charging from a USB Port
- BU-412: Charging without Wires
- BU-413: Charging with Solar, Turbine
- BU-413a: How to Store Renewable Energy in a Battery
- BU-414: How do Charger Chips Work?
- BU-415: How to Charge and When to Charge?
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Discharge Methods 4>
- BU-501: Basics about Discharging
- BU-501a: Discharge Characteristics of Li-ion
- BU-502: Discharging at High and Low Temperatures
- BU-503: Determining Power Deliver by the Ragone Plot
- BU-504: How to Verify Sufficient Battery Capacity
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"Smart" Battery 4>
- BU-601: How does a Smart Battery Work?
- BU-602: How does a Battery Fuel Gauge Work?
- BU-603: How to Calibrate a “Smart” Battery
- BU-603a: Calibrating SMBus Batteries with Impedance Tracking
- BU-604: How to Process Data from a “Smart” Battery
- Testing and Calibrating Smart Batteries
-
From Birth to Retirement 4>
- BU-701: How to Prime Batteries
- BU-702: How to Store Batteries
- BU-703: Health Concerns with Batteries
- BU-704: How to Transport Batteries
- BU-704a: Shipping Lithium-based Batteries by Air
- BU-704b: CAUTION & Overpack Labels
- BU-704c: Class 9 Label
- BU-704d: NFPA 704 Rating
- BU-704e: Battery for Personal and Fleet Use
- BU-705: How to Recycle Batteries
- BU-705a: Battery Recycling as a Business
- BU-706: Summary of Do's and Don'ts
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How To Prolong Battery Life 4>
-
General 4>
- BU-801: Setting Battery Performance Standards
- BU-801a: How to Rate Battery Runtime
- BU-801b: How to Define Battery Life
- BU-802: What Causes Capacity Loss?
- BU-802a: How does Rising Internal Resistance affect Performance?
- BU-802b: What does Elevated Self-discharge Do?
- BU-802c: How Low can a Battery be Discharged?
- BU-803: Can Batteries Be Restored?
- BU-803a: Cell Matching and Balancing
- BU-803b: What causes Cells to Short?
- BU-803c: Loss of Electrolyte
-
Lead Acid 4>
- BU-804: How to Prolong Lead-acid Batteries
- BU-804a: Corrosion, Shedding and Internal Short
- BU-804b: Sulfation and How to Prevent it
- BU-804c: Acid Stratification and Surface Charge
- BU-805: Additives to Boost Flooded Lead Acid
- BU-806: Tracking Battery Capacity and Resistance as part of Aging
- BU-806a: How Heat and Loading affect Battery Life
-
Nickel-based 4>
- BU-807: How to Restore Nickel-based Batteries
- BU-807a: Effect of Zapping
-
Lithium-ion 4>
- BU-808: How to Prolong Lithium-based Batteries
- BU-808a: How to Awaken a Sleeping Li-ion
- BU-808b: What Causes Li-ion to Die?
- BU-808c: Coulombic and Energy Efficiency with the Battery
- BU-809: How to Maximize Runtime
- BU-810: What Everyone Should Know About Aftermarket Batteries
- BU-811: Assuring Minimum Operational Reserve Energy (MORE)
-
Battery Testing and Monitoring 4>
- BU-901: Fundamentals in Battery Testing
- BU-901b: How to Measure the Remaining Useful Life of a Battery
- BU-902: How to Measure Internal Resistance
- BU-902a: How to Measure CCA
- BU-903: How to Measure State-of-charge
- BU-904: How to Measure Capacity
- BU-905: Testing Lead Acid Batteries
- BU-905a: Testing Starter Batteries in Vehicles
- BU-905b: Knowing when to Replace a Starter Battery
- BU-906: Testing Nickel-based Batteries
- BU-907: Testing Lithium-based Batteries
- BU-907a: Battery Rapid-test Methods
- BU-907b: Advancements in Battery Testing
- BU-907c: Cloud Analytics in Batteries
- BU-908: Battery Management System (BMS)
- BU-909: Battery Test Equipment
- BU-910: How to Repair a Battery Pack
- BU-911: How to Repair a Laptop Battery
- BU-915: Testing Battery with EIS
- BU-916: Deep Battery Diagnostics
- BU-917: In Search for Performance Transparency with Batteries
- BU-918: Battery Endurance Plan
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Amazing Value of a Battery 4>
- BU-1001: Batteries in Industries
- BU-1002: Electric Powertrain, then and now
- BU-1002a: Hybrid Electric Vehicles and the Battery
- BU-1002b: Environmental Benefit of the Electric Powertrain
- BU-1003: Electric Vehicle (EV)
- BU-1003a: Battery Aging in an Electric Vehicle (EV)
- BU-1004: Charging an Electric Vehicle
- BU-1005: Does the Fuel Cell-powered Vehicle have a Future?
- BU-1006: Cost of Mobile and Renewable Power
- BU-1007: Net Calorific Value
- BU-1008: Working towards Sustainability
- BU-1009: Battery Paradox - Afterword
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Information 4>
- BU-1101: Glossary
- BU-1102: Abbreviations
- BU-1103: Bibliography
- BU-1104: About the Author
- BU-1105: About Cadex (Sponsor)
- BU-1106: Author's Creed
- BU-1107: Disclaimer
- BU-1108: Copyright
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Learning Tools 4>
- BU-1501 Battery History
- BU-1502 Basics about Batteries
- BU-1503 How to Maintain Batteries
- BU-1504 Battery Test & Analyzing Devices
- BU-1505 Short History of Cadex
-
Battery Articles 4>
- Perception of a Battery Tester
- Green Deal
- Risk Management in Batteries
- Predictive Test Methods for Starter Batteries
- Why Mobile Phone Batteries do not last as long as an EV Battery
- Battery Rapid-test Methods
- How to Charge Li-ion with a Parasitic Load
- Ultra-fast Charging
- Assuring Safety of Lithium-ion in the Workforce
- Diagnostic Battery Management
- Tweaking the Mobile Phone Battery
- Battery Test Methods
- Battery Testing and Safety
- How to Make Battery Performance Transparent
- Battery Diagnostics On-the-fly
- Making Battery State-of-health Transparent
- Batteries will eventually die, but when and how?
- Why does Pokémon Go rob so much Battery Power?
- How to Care for the Battery
- Tesla’s iPhone Moment — How the Powerwall will Change Global Energy Use
- Painting the Battery Green by giving it a Second Life
- Charging without Wires — A Solution or Laziness
- What everyone should know about Battery Chargers
- A Look at Cell Formats and how to Build a good Battery
- Battery Breakthroughs — Myth or Fact?
- Rapid-test Methods that No Longer Work
- Shipping Lithium-based Batteries by Air
- How to make Batteries more Reliable and Longer Lasting
- What causes Lithium-ion to die?
- Safety of Lithium-ion Batteries
- Recognizing Battery Capacity as the Missing Link
- Managing Batteries for Warehouse Logistics
- Caring for your Starter Battery
- Giving Batteries a Second Life
- How to Make Batteries in Medical Devices More Reliable
- Possible Solutions for the Battery Problem on the Boeing 787
- Impedance Spectroscopy Checks Battery Capacity in 15 Seconds
- How to Improve the Battery Fuel Gauge
- Examining Loading Characteristics on Primary and Secondary Batteries
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Language Pool 4>
- BU-001: Compartir conocimiento sobre baterías
- BU-002: Introducción
- BU-003: Dedicatoria
- BU-104: Conociendo la Batería
- BU-302: Configuraciones de Baterías en Serie y Paralelo
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Batteries in a Portable World book 4>
- Change-log of “Batteries in a Portable World,” 4th edition: Chapters 1 - 3
- Change-log of “Batteries in a Portable World,” 4th edition: Chapters 4 - 10